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I am booked for PEO at Croydon tomorrow.

It has just occurred to me that no one will be home to receive my BRP (assuming my application is approved) during working hours. Has anyone experienced the same issue and how did you deal with it? Should I give my work address in 1.16 (Name and address in the UK for all correspondence about your application if different from 1.13), or is that something they check on the day?

Apart of home address the application form always give opportunity to use other alternative address for correspondence. Usually DX courier is being used for BRP delivery which need the main applicant presence at home otherwise a letter of authority along with some proof of ID can be given to anyone who receive it in the absence of applicant.